Dynamic Configurational Isomerism of a Stable Pentaorganosilicate
نویسندگان
چکیده
منابع مشابه
Keto-Enol-Tautomerism and Configurational Isomerism of 2,6-Disubstituted 4-Piperidone-3,5-dicarboxylates [1]
The dialkyl 2,6-dialkylsubstituted 4-piperidone-3,5-dicarboxylates were synthesized by a Mannich procedure. Depending on the substitution at the nitrogen keto-enol-tautomerism and a configurational isomerism at C 2 is observed. The structure o f the N-substituted piperidone 24 E (C 18H29N 0 5) has been determined by X-ray analysis: it is characterized by an enol structure o f the /?-ketoester a...
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ژورنال
عنوان ژورنال: Angewandte Chemie
سال: 2004
ISSN: 0044-8249,1521-3757
DOI: 10.1002/ange.200353006